You could copy and paste the shortcut, and delete the lines to do with EMM386 and HIMEM

Here are mine, it has a menu and you can choose what memory you want:

CONFIG:

[COMMON] DOS=NOAUTO DOS=HIGH,UMB FILES=30 BUFFERS=30 LASTDRIVE=H DEVICE=C:\WINDOWS\SETVER.EXE […]
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[COMMON]
DOS=NOAUTO
DOS=HIGH,UMB
FILES=30
BUFFERS=30
LASTDRIVE=H
DEVICE=C:\WINDOWS\SETVER.EXE

[menu]
menuitem=EMC, Expanded memory + Mouse + CD-ROM
menuitem=XMC, Extended memory + Mouse + CD-ROM
menuitem=CMC, Conventional Memory only + Mouse + CD-ROM
menuitem=EM, Expanded memory + Mouse
menuitem=XM, Extended memory + Mouse
menuitem=CM, Conventional memory only + Mouse

menudefault=EMC,10

[EMC]
DEVICE=C:\WINDOWS\HIMEM.SYS /TESTMEM:OFF
DEVICE=C:\WINDOWS\EMM386.EXE RAM
DEVICEHIGH=C:\DRIVERS\VIDECDD.SYS /D:OPTICAL

[XMC]
DEVICE=C:\WINDOWS\HIMEM.SYS /TESTMEM:OFF
DEVICEHIGH=C:\DRIVERS\VIDECDD.SYS /D:OPTICAL

[CMC]
DEVICEHIGH=C:\DRIVERS\VIDECDD.SYS /D:OPTICAL

[EM]
DEVICE=C:\WINDOWS\HIMEM.SYS /TESTMEM:OFF
DEVICE=C:\WINDOWS\EMM386.EXE RAM

[XM]
DEVICE=C:\WINDOWS\HIMEM.SYS /TESTMEM:OFF

[CM]

AUTOEXEC

LH C:\DRIVERS\CTMOUSE.EXE /R2 GoTo %config% :EMC :XMC :CMC LH C:\WINDOWS\COMMAND\MSCDEX.EXE /D:OPTICAL :EM :XM :CM […]
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LH C:\DRIVERS\CTMOUSE.EXE /R2
GoTo %config%
:EMC
:XMC
:CMC
LH C:\WINDOWS\COMMAND\MSCDEX.EXE /D:OPTICAL
:EM
:XM
:CM

MS-DOS mode can be a bit tricky. So I made a tutorial a while ago: https://www.youtube.com/watch?v=Y6HzttM6wS0

So I decided to try out this configuration you posted though I had to copy Himem and EMM386 to a DOS Folder I had to make before the other memory settings worked
However, the CD Drivers didn't worked when I tried this alternate config for some reason (It worked in the configuration settings I used previously)

CompuClassics wrote:

So I decided to try out this configuration you posted though I had to copy Himem and EMM386 to a DOS Folder I had to make before the other memory settings worked
However, the CD Drivers didn't worked when I tried this alternate config for some reason (It worked in the configuration settings I used previously)

Oh dear, I pasted the startup files for MS-DOS 6.22. Sorry about that.

I've changed the original post.

Thanks:)
I'll go try out the new corrected settings now
(EDIT: They finally work now)

CompuClassics wrote:

However, I also want to be able to boot without any memory managers whatsoever (For games that make use of their own managers like Zone66 or Ultima7)

Unless you actually intend to play those games specifically, it's probably not worth worrying about. (In particular, Zone 66 doesn't require a CD-ROM drive, and much the same probably applies to whatever other games out there don't like memory managers. U7 would be the exception, but even if you don't want to use Exult for Ultima 7, U7Run will work just as well and let you use the original engine.)