The ATI card seems to be a 8514A clone. It was probably working all the time.
Plug it in with another VGA card and use a application that utilizes the 8514A.
For a first try Dosshell with the 8514A Video driver is sufficient.
Or try Win 3.1 with the 8514A driver for video.
(Original 8514A: http://mail.lipsia.de/~enigma/neu/ps2/8514a.jpg)
I think you don't require to hook the Vesa connector...
Only if you want to plug the monitor cable permanently to the Ati card. It resembles probably only the VGA through that is implemented on PS/2 systems directly as MCA Bus feature.
I would go for the Paradise PVGA1A first. As early ISA video card it's very ok.
Some time ago I have done some benches with Duke3D, also with a few ISA cards:
Duke Nukem 3D mit DNRATE / P166MMX
Card 320x200 640x480
V7 Vega ISA 9 -
http://mail.lipsia.de/~enigma/neu/pics/cl_vga.jpg
Paradise PVGA1A ISA 23 -
http://mail.lipsia.de/~enigma/neu/pics/pvga1a.jpg
WDC90C11 ISA 32 9 +
ET4000AX ISA 14 3 with VESA 1.2 from SC2000
early version 3 with UniVBE 6.70
http://mail.lipsia.de/~enigma/neu/pics/et4000.jpg
other ET4000AX 32 9 UniVBE6.70
1 MB 34 UniVBE 6.70
Trident
TVGA 8800C 512kB 17