Are you certain that the Turtle Beach Malibu Surround 64 has a Kurzweil synthesizer? It seems that there is not much information available about the TB Malibu Surround 64, but I found this text in the knowledge base on the TB website:
"The Malibu Surround 64 is the latest ISA soundcard designed by Turtle Beach. It incorporates a software synthesizer (the Wavestream synth), SRS Surround decoding, and surprisingly clean audio quality for such an inexpensive soundcard."
That would suggest that it does not use a Kurzweil synth, or at least not a hardware implementation.
I own the Turtle Beach Multisound Pinnacle Project Studio, which basically consists of the TB Pinnacle soundcard and the TB Kurzweil HOMAC daughterboard. The TB Pinnacle is identical to the TB Fiji, but it expands it by incorporating yet another Kurzweil synth (Kurzweil MA-1) and an EIDE connector on-board. The main Kurzweil MA-1 synth sounds fairly good, allows up to 48MB of sample RAM and has individual reverb and chorus settings for each MIDI channel. I was not so impressed with the HOMAC though. It didn't sound very balanced and the effects were pretty bad. Furthermore, it only allows a global effects setting, so you can't adjust the reverb and chorus for each individual instrument.
As for the DOS support, I find the TB Pro Series all quite lacking in this department. It is clear that these cards were aimed at musicians, rather than gamers. Therefore, they have very limited DOS support. I had a quick look in the manual of the TB Pinnacle, but nothing states that you can use either the on-board or the daughterboard synth in a real DOS environment. They only explain how to use the EIDE connector and the joystick port in real DOS. Therefore, the daughterboard on the Fiji will probably not work in real DOS.
Hope that answers your questions. 😀
Edit: Another page in their knowledge base has this to say about the Malibu Surround 64:
"* Legendary Kurzweil(R) hardware wavetable synthesis with 4 MB of instrument samples compressed to 2 MB."
So they either failed to mention on the first page that, in addition to the software synth, it also has a hardware synth, or the second page is incorrect. I'm assuming that the second page is correct though, because it lists all the specifications of the card. Also, from the rather vague pictures on the web, it looks like it might use the same chips as the HOMAC. Furthermore, the HOMAC also has 4MB of samples compressed to 2MB. Would you mind taking a picture of the TB Malibu Surround 64 and upload it to your website? I'd like to see a proper picture of it. 😀