To add to that: The colors on those cables have meaning. Yellow is +12V, red is +5V. Black is ground. So both of those connectors carry 5V and 12V.
The only time I've ever seen a power supply with specific +5V connectors is when it has a 2-pin header connector for the turbo LED display. (And I've added connectors to my AT supplies for that purpose as well, while I was in there refurbishing them anyway.) I don't know of any common adapters that would convert Molex to 2-pin female header, but I did have to make one a few years back for a mini ITX PC that booted from a Compact Flash card via an IDE to CF adapter board with male pin headers for its power input.
Sometimes a supply will have a +12V connector meant to power a CPU fan -- it's just a motherboard fan connector on a cable, with the RPM sense pin unconnected. But I doubt that's what you're referring to here. 😀