VOGONS


First post, by songoffall

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This will be a short explanation on certain failure modes of capacitors, for people to understand the process better. Also to explain the "capacitor plague". Feel free to add to it - I don't claim to know it all or have the ability to put it into a single post.

What is a capacitor?
A capacitor is essentially two electrically conductive surfaces, called plates, separated by a non-conductive dielectric. When you apply different charges to these two surfaces, those charges are drawn to each other, so the capacitor can hold charge.

Filtering capacitors, for example, will absorb charge when the current goes up and give up charge when the current goes down, thus filtering out changes or noise in currents.

There are polarized and non-polarized capacitors: polarized capacitors have designated positive and negative plates, called anode and cathode.

If you take the simplest capacitor, where two plates are separated by air, glass, vacuum, silicon, these are non-polarized, and it doesn't matter which plate takes positive or negative charge.

Ceramic capacitors and film capacitors work the same way.

Electrolytic capacitors are different.

E.g. alumnium electrolytic capacitors are two aluminum plates coiled around each other with paper between them. Then the paper is soaked with conductive electrolyte. Then low voltage is given to the plates - at this point what we have is not a capacitor and the current can flow freely from plate to plate through the electrolyte. But the process causes the electrolyte to react with the positive - anode - plate, and build a non-conductive aluminum oxide layer on it. Then the current is raised to the operating voltage of the capacitor.

The thicker the oxide layer - the higher the voltage, at which the capacitor can operate, but also the lower the capacitance - how much charge the capacitor can hold. Connecting electrolytic capacitors backwards will swap the anode and the cathode, but because the conditions of the process are not the same as in the factory, it will be too fast, consume a lot of power and transform it into heat, there will be gas buildup from the chemical reaction and the capacitor will fail. And even if it doesn't, the end result will not fit the original specs.

While there's still electrolyte inside the capacitor and the capacitor is operated within specs, the oxide layer will keep reforming, which is why aluminium electrolytic capacitors are self-healing.

Tantalum caps are also electrolytic capacitors, except a different method and different materials are used when creating them, but while they might look like ceramic or film caps, they are polarized.

How capacitors fail
1. Dielectric breakdown. Air is a dielectric, but if you charge two plates with opposing charges and keep raising the voltage, an electric arch will form between those plates, and air will start behaving like a conductor. Every dielectric has its own dielectric breakdown voltage, and a capacitor's dielectric breakdown voltage depends on the dielectric material, its thickness and the surface area of the plates. Which in turn may be affected by the conditions in which the capacitor operates, and the age of the capacitor.

Because even at breakdown dielectrics have a lot of resistance, a lot of heat is released, and causes the capacitor to lose its integrity and fail.

In common capacitors, it may cause the plates to make contact and short. This is what happens with most capacitors when they fail due to dielectric breakdown.

In safety capacitors, the failure does not cause a short but an open circuit - they are built so when the capacitor fails, the plates are drawn apart. REEFA caps, known for releasing their magic smoke and wonderful aroma at failure, are safety caps.

2. Electrolytic capacitors have additional modes of failure. In aluminium electrolytic capacitors, the oxide layer will keep deteriorating without the self-healing while in operation. And when you turn on an old device that has been in storage for years without safely reforming the capacitors, they will reform rapidly, which will cause a buildup of hydrogen gas and the temperature will raise inside the capacitor. This, in turn, may cause the capacitor to bulge and even bubbles to form between plates driving them apart. Some capacitors can even explode from high internal pressure or leak electrolyte on the PCB.

If kept in operation, electrolytic capacitors will keep self-healing until the electrolyte is spent and the capacitor starts drying up. It will drift out of spec and eventually fail, but in a non-violent way.

The capacitor plague
The capacitor plague refers to the earlier than expected failures of electrolytic capacitors in the first half of 2000s. Usually these are capacitors of Taiwanese origin.

Bad electrolyte causes corrosion inside the capacitor and a buildup of gas which causes bulging, ruptured or leaking capacitors even in normal operation. I have a bunch of Radeon 9200SE cards from the same era and every single capacitor on them has failed. Same often goes for motherboards from early 2000s.

There's a theory that Taiwanese manufacturers tried to steal the electrolyte formula from Japan and the formula was miscopied, but I don't really know the details of that story.

But, in the end, the capacitor plague was one of the factors that cemented the solid reputation of Japanese capacitors.

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Reply 1 of 4, by mkarcher

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Basically, you got most of the concepts correct, but I have a few nit-picks:

songoffall wrote on 2024-03-03, 09:51:

Filtering capacitors, for example, will absorb charge when the current goes up and give up charge when the current goes down, thus filtering out changes or noise in currents.

It's the voltage that causes a capacitor to absorb or release charge. The capacitance is measured in Farad, which is Ampere-seconds (charge) per Volt. There is current flow when the capacitor absorbs or releases charge, but the primary idea of a filter capacitor is stabilizing the voltage by releasing charge when the voltage goes down because the current used by other devices (like the chip next to the capacitor) goes up. The capacitor next to a chip can provide the required charge quicker than the power supply can react, thus making sure the chip doesn't malfunction because short-term power demand spikes can not be dealt with.

songoffall wrote on 2024-03-03, 09:51:

Connecting electrolytic capacitors backwards will swap the anode and the cathode, but because the conditions of the process are not the same as in the factory, it will be too fast, consume a lot of power and transform it into heat, there will be gas buildup from the chemical reaction and the capacitor will fail. And even if it doesn't, the end result will not fit the original specs.

The gas production need not even be from a chemical reaction. The heat by itself is enough to evaporate the electrolyte chemically unchanged, which is just a physical effect.

songoffall wrote on 2024-03-03, 09:51:

Because even at breakdown dielectrics have a lot of resistance, a lot of heat is released, and causes the capacitor to lose its integrity and fail.

I would not call it "a lot" of resistance. If the dielectric would have "a lot" of resistance (like some kilo-ohms), the current would be low enough to not provide any significant amount of heat. At 12V and 1 kiloohm, you get 12mA current, which would be around 150mW. The resistance is way lower (maybe a couple of ohms) to cause the effect you describe.

songoffall wrote on 2024-03-03, 09:51:

In safety capacitors, the failure does not cause a short but an open circuit - they are built so when the capacitor fails, the plates are drawn apart. REEFA caps, known for releasing their magic smoke and wonderful aroma at failure, are safety caps.

The company that manufactured these capacitors is called RIFA, not REEFA. As this is a Swedish name, they are pronounced in a way as English-speaking people would pronounce "Reefa". The way these caps fail is not how safety caps are supposed to fail and actually an example for a "saftety cap" being quite unsafe. Safety caps are supposed to lose capacity and go open circuit gradually and without any firework effects when excessive leakage occurs. On the other hand, these RIFA caps go short, develop a lot of heat and smoke, and the circuit is opened up by a different device, most of the times a fuse or the main circuit breaker of your electrical supply. On the plus side, the materials the RIFA cap is built from is extremely hard to ignite (on purpose!), so there won't be a sustained fire after the circuit is interrupt by an external devices, which will still provide some basic level of safety.

songoffall wrote on 2024-03-03, 09:51:

If kept in operation, electrolytic capacitors will keep self-healing until the electrolyte is spent and the capacitor starts drying up. It will drift out of spec and eventually fail, but in a non-violent way.

You can't be sure it's non-violent. If electrolytic capacitors are used as output capacitors in switch-mode regulators, they have a lot of current repeatedly charging and discharging it. They stay cool because their resistance ("ESR") is extremely low, so the high current causes only a very low voltage drop, and as power is voltage multiplied by current, the power dissipated in that capacitor is also low. While the capacitor dries up, there is less electrolyte, and the resistance rises. While the increased resistance will lower the current the capacitor will absorb or release, the voltage required to do that is increasing, and the product of voltage and current starts going up first, increaing heat in the capacitor. Oftentimes, the heat will just accelerate the process that degrades the electrolyte in a way that is still "under control", and just cause some bulging of the caps and possibly opening a tiny hole in the pressure relief safety stuff, but in some circumstances the heat might be sufficient to cause sudden electrolyte evaporation and mechanical failure shorting the cap.

Reply 2 of 4, by dionb

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In addition, failure of caps can cause adjacent components to go out of spec too, which - particularly in power regulation circuits - can lead to fireworks. I've seen a failed electrolytic cap in a motherboard power regulator cause the MOSFET next to it to overheat so badly it melted through the PCB. That's an outlier, but even where the cap itself fails reasonably gracefully it's no guarantee the whole circuit will do so.

Reply 3 of 4, by songoffall

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dionb wrote on 2024-03-03, 10:52:

In addition, failure of caps can cause adjacent components to go out of spec too, which - particularly in power regulation circuits - can lead to fireworks. I've seen a failed electrolytic cap in a motherboard power regulator cause the MOSFET next to it to overheat so badly it melted through the PCB. That's an outlier, but even where the cap itself fails reasonably gracefully it's no guarantee the whole circuit will do so.

True. In particular, the noise the capacitor was supposed to filter can make sensitive parts like MOSFET power regulators go haywire.

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Reply 4 of 4, by songoffall

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mkarcher wrote on 2024-03-03, 10:37:
Basically, you got most of the concepts correct, but I have a few nit-picks: […]
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Basically, you got most of the concepts correct, but I have a few nit-picks:

songoffall wrote on 2024-03-03, 09:51:

Filtering capacitors, for example, will absorb charge when the current goes up and give up charge when the current goes down, thus filtering out changes or noise in currents.

It's the voltage that causes a capacitor to absorb or release charge. The capacitance is measured in Farad, which is Ampere-seconds (charge) per Volt. There is current flow when the capacitor absorbs or releases charge, but the primary idea of a filter capacitor is stabilizing the voltage by releasing charge when the voltage goes down because the current used by other devices (like the chip next to the capacitor) goes up. The capacitor next to a chip can provide the required charge quicker than the power supply can react, thus making sure the chip doesn't malfunction because short-term power demand spikes can not be dealt with.

songoffall wrote on 2024-03-03, 09:51:

Connecting electrolytic capacitors backwards will swap the anode and the cathode, but because the conditions of the process are not the same as in the factory, it will be too fast, consume a lot of power and transform it into heat, there will be gas buildup from the chemical reaction and the capacitor will fail. And even if it doesn't, the end result will not fit the original specs.

The gas production need not even be from a chemical reaction. The heat by itself is enough to evaporate the electrolyte chemically unchanged, which is just a physical effect.

songoffall wrote on 2024-03-03, 09:51:

Because even at breakdown dielectrics have a lot of resistance, a lot of heat is released, and causes the capacitor to lose its integrity and fail.

I would not call it "a lot" of resistance. If the dielectric would have "a lot" of resistance (like some kilo-ohms), the current would be low enough to not provide any significant amount of heat. At 12V and 1 kiloohm, you get 12mA current, which would be around 150mW. The resistance is way lower (maybe a couple of ohms) to cause the effect you describe.

songoffall wrote on 2024-03-03, 09:51:

In safety capacitors, the failure does not cause a short but an open circuit - they are built so when the capacitor fails, the plates are drawn apart. REEFA caps, known for releasing their magic smoke and wonderful aroma at failure, are safety caps.

The company that manufactured these capacitors is called RIFA, not REEFA. As this is a Swedish name, they are pronounced in a way as English-speaking people would pronounce "Reefa". The way these caps fail is not how safety caps are supposed to fail and actually an example for a "saftety cap" being quite unsafe. Safety caps are supposed to lose capacity and go open circuit gradually and without any firework effects when excessive leakage occurs. On the other hand, these RIFA caps go short, develop a lot of heat and smoke, and the circuit is opened up by a different device, most of the times a fuse or the main circuit breaker of your electrical supply. On the plus side, the materials the RIFA cap is built from is extremely hard to ignite (on purpose!), so there won't be a sustained fire after the circuit is interrupt by an external devices, which will still provide some basic level of safety.

songoffall wrote on 2024-03-03, 09:51:

If kept in operation, electrolytic capacitors will keep self-healing until the electrolyte is spent and the capacitor starts drying up. It will drift out of spec and eventually fail, but in a non-violent way.

You can't be sure it's non-violent. If electrolytic capacitors are used as output capacitors in switch-mode regulators, they have a lot of current repeatedly charging and discharging it. They stay cool because their resistance ("ESR") is extremely low, so the high current causes only a very low voltage drop, and as power is voltage multiplied by current, the power dissipated in that capacitor is also low. While the capacitor dries up, there is less electrolyte, and the resistance rises. While the increased resistance will lower the current the capacitor will absorb or release, the voltage required to do that is increasing, and the product of voltage and current starts going up first, increaing heat in the capacitor. Oftentimes, the heat will just accelerate the process that degrades the electrolyte in a way that is still "under control", and just cause some bulging of the caps and possibly opening a tiny hole in the pressure relief safety stuff, but in some circumstances the heat might be sufficient to cause sudden electrolyte evaporation and mechanical failure shorting the cap.

Thanks for your input.

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