Hi Harry Potter,
are you looking for documentation about the win32 API or about a 64 bit version of Open Watcom?
The main source for documentation about the win32 API is here: https://learn.microsoft.com/
However, it is pretty hard to browse this website if you are looking for a general overview. For example if you like to know how to interact with files (open a file, read a file, write to a file, close a file) then finding the right links to click on to get to the relevant articles is difficult. At least in my opinion.
A different approach would be to use the program "Dependency Walker" to check which functions a certain dll exports. For example if you check the exports of kernel32.dll you will find functions like "CreateFileA", "CreateFileW" and "CloseFile". If you have found a function that might suit what you need, then you can use a search engine to search for "CreateFileW function" as an example. You will probably get the article about this function on learn.microsoft.com as one of the first search results. When reading the article you will figure out that this function is for creating new files and also for opening existing files.
When working with old operating systems this documentation is rather unreliable. For example the article about the CreateFileW-function states, that this function was introduced with Windows XP and Windows Server 2003. However, this is not true. The function existed long before.
When you need documentation offline then learn.microsoft.com isn't so good either. The website allows exporting as pdf but it's a mess. It will create one pdf for one function. Or one pdf with many functions. But you can't download a chm file with articles, subarticles, categories and so on. But I guess that this type of documentation also exists from the old days when the Internet wasn't as popular as it is today.
Another approach is to explain your goal to chat.qwen.ai. Qwen will output some code that goes in the general direction. The code is usually full of bugs, but you will see which functions Qwen uses to reach the goal. So you can get a clearer picture about how to get there. However, then it is up to you to read the documentation about these functions.
Qwen might be convincing with it's words but has no problem with lying and making stuff up, presenting direct quotes from the official documentation which can not be found if someone looks them up. So be careful when using Qwen or similar programs which claim to be intelligent.
To use Qwen you need to register an account with an email address that works at least once for the activation. Besides of the email address it's free of charge.