The Pentium 4 630 is a Prescott based model with a TDP of 84 watts, high but should be still manageable.
Looking at the picture it does seem to be a little tight inside here, the heat sink on the CPU seems to me to be made of mostly aluminium and straight fins in one direction, some improvements might be made by switching it to a mostly copper one, and also because it is an ingress fan then it might be better to have one which not only have straight fins in one direction but some openings in the other sides to better spread the airflow around the CPU.
If there is no place for more case fans I notice that there is an empty PCI slot next to the graphics card, as the graphics card is in the way between this slot and the CPU the location is not ideal, but you might be able to fit a PCI slot fan(You can find these on multiple online stores/marketplaces including Amazon) here to exhaust heat from the case.