Manuals dating to the release of a motherboard are rarely a good indication of the maximum capabilities as they can - by definition - only tell you about CPUs that were available at time of writing, whereas newer CPUs may work out of the box, may work after a BIOS update or it might be possible to get to work with various hacks.
So let's see what we have here...
This is a pretty generic i430VX board. In retrospect the i430VX platform is generally seen as pretty underwhelming, only adding (primitive) SDRAM onto the featureset of the older (and much more revolutionary) i430FX without addressing any of its shortcuts (mainly around caching). In its day though, it was the fastest money could buy and it wasn't even particularly expensive (unlike its i430HX sibling). So potentially good for nostalgic reasons. Not great for pushing the envelope though.
In terms of CPU support, i430VX gives you a split voltage plane and official support for 66MHZ FSB, but the silicon will usually handle 75MHz if there is circuitry present that can supply it.
This board has documented voltage settings down to 2.5V and documented FSB settings of 50, 60 an 66MHz.
So what could run with those? 2.5V is within tolerance for the K6-3 CPU. It re-maps 2.0x multiplier to 6.0x, so you could run at 6x0x66MHz=400MHz with a K6-3 without modifications, at least, if the BIOS accepts it.
Now, could you push it further? For that, we'd need some detailed photographs of your specific board, in particular the area around the jumpers for bus speed and voltage.
The two jumpers for bus speed give four logical options even though only three are documented. Depending on the PLL chip they connect to, the fourth option would either be 55MHz (not very useful) or 75MHz (which gives you 12.5% more speed vs 66MHz, although it will also overclock PCI and possibly ISA buses at the same time)..
As for voltage, that looks more complex. Sometimes using a resistor instead of a jumper to connect pins will give you a lower voltage. If you can get it down to 2.2V, you could use ubiquitous K6-2 CPUs. Not as fast as K6-3, but much easier/cheaper to find. At 2.0V you could safely try K6-2+/K6-3+, although it's unlikely they would work without BIOS modification. But even if you could get the right voltage, it's an open question whether the VRM/MOSFETs could handle the added current of these faster CPUs on lower voltage. So pics of the components needed before definite advice here.
However maybe a step back: this is a pretty unremarkable board and by no means well-suited to pushing the envelope when it comes to CPUs. Why do you want to try that with this particular board? The answer to that might also let us give you more relevant tips.