Mid 1990s? That straddles the border between DOS and firmly 2D (or at least: no 3D acceleration) and Windows supporting acceleration. This Deskpro 2000 would be excellent at the former and pretty crap at the latter. How crap depends on the motherboard chipset. Later Deskpro 2000 used the quite adequate AMD640/Via VP2, earlier ones used the abominable Compaq Triflex.
If you want to span a considerable range of performance and operating systems, you generally want a very controllable system at the higher end of your range. A Deskpro 2000 is hardly high-end and like other OEM systems offers very limited configuration options. I'd recommend pretty much any contemporary noname system over this one, and actually I'd recommend two separate systems - a DOS system with VGA & (ISA) sound aimed at the last DOS titles (this Deskpro2000 could do that) and a Win9x system with (accelerated) VGA and 3D sound aimed at that stuff. I'd generally suggest something from the P3-era for that.
Given that context, what do you expect to gain by increasing the video memory of the onboard CL5434? All that will give you is higher supported resolutions/colour depths. For DOS it's pretty irrelevant as hardly any games even come close to the limits of 1MB (640x480@24b, 800x600@16b, 1024x768@8b), but for Windows, running a desktop at either 800x600@16b or 1024x768@8b is painful. 2MB lets you go to 1024x768@16b, whcih is good enough for most period-correct work. What the extra memory won't give you is any extra performance.
For more performance, you'd need another card. That Verite Rendition V1000 is a bit of an oddball, but a definite improvement over the CL5434 in (Windows/DX) performance and an excellent 1996 option. Chuck in a Voodoo2 for 1998 and you can run pretty much anything that a CPU that could fit in the Deskpro 2000. And of course, 4MB lets you run 1024x767@24b on the desktop, which is nice.
For DOS the Verite's not going to make much difference. The compatibility matrix shows it has similar compatibility to the GD5434, which is slightly above average - not as good as 3dfx, nVidia or S3 but much better than ATi or Matrox chipsets. If you hit issues, you can always try with the onboard CL5434 instead.