Unless you know what you're doing (i.e. you're trying to overvolt/undervolt the CPU), the voltage should be set to auto on the slotket, which means that the CPU will send its default voltage request signal to the motherboard and the motherboard will provide said voltage.
If the motherboard can't provide the required voltage (which is usually the case with Coppermine CPUs and some older 440BX motherboards that only support voltages down to 1.8V), the CPU will remain unpowered and, naturally, you will not get a POST.
Regarding multipliers - all of these CPUs have a factory hard-locked multiplier, so it doesn't matter what multiplier you set on the motherboard itself.
If your Pentium 3 600 booted at 400 MHz, that means the FSB was set at 66 MHz on the motherboard (again, the multiplier is fixed and can't be changed no matter what you try).
2 x PLCC-68 / 4 x PGA132 / 5 x Skt 3 / 1 x Skt 4 / 9 x Skt 7 / 12 x SS7 / 1 x Skt 8 / 14 x Slot 1 / 6 x Slot A
5 x Skt 370 / 8 x Skt A / 2 x Skt 478 / 2 x Skt 754 / 3 x Skt 939 / 7 x LGA775 / 1 x LGA1155
Current PC: Ryzen 7 9800X3D
Backup: Ryzen 7 5800X3D