The GeForce 4 Ti 4200 does not have a built-in temperature sensor that is accessible via software.
Furthermore, from my experience, those cards run warm, if not hot. That means the whole PCB, not only the GPU. They have a fairly high idle consumption. So if you want to do your card a favor, ensure some good airflow. Using a larger active cooling solution, either by strapping a big fan on it or like Repo man suggested, a bigger aftermarket cooler with fan, should keep her running on decent temperates.
Don't bother recapping the card if there are no obvious damages to the caps and if there is no issue in the cards behavior. You'll put 20 year old hardware to thermal stress without any gain. Repair stuff when it's broken, not when it seems attractive.