Xonar DG should provide better quality output, but I don't know how noticeable it will be. The DG also has a headphone amplifier, which could make a difference in quality as well, especially if you connect headphones directly to your sound card.
I guess it comes down to if the Audigy has any special hardware sound features (EAX 3.0 is basically it) that you're going to make use of. Personally, I used a ton of sound cards through the 1999-2005 era and was never all that pleased with environmental effects, aside from Aureal's A3D 2.0, so I don't think you'll be missing much with the Xonar's slightly more limited EAX support. Even the X-Fi with EAX 5.0 Advance HD or whatever it was called didn't make any impression on me whatsoever.
As for capacitors, I wouldn't bother.
I think someone with some good capacitance measuring equipment should test caps from various pieces of hardware, from different eras to see if there is any legitimacy to the "recap everything" philosophy that has spread across the internet (likely starting in an audiophile community). Caps from the capacitor-plague-era, clearly defective caps, caps in circuits with other defective caps, devices with obvious problems, caps that are known to have problems, devices that are 40-50 years old... I can understand. But preemptively recapping entire boards with no measurable change in performance or reliability seems like an unnecessary risk to the equipment in question, at least for most of us mere mortals that can't recap an entire board perfectly in 15 minutes.