Okay one last bump. Just need to document this in case anyone is in the same situation as I am. I don't think my post is THAT far back.
Thanks to some very knowledgeable and kind people on The Retro Web discord server, it would seem that changing the values for these registers while the OS is loaded is too late. It must be done earlier in the boot process.
Also it has been determined that is not simply a matter of using MODBIN to show some hidden menus. The menu settings to enable UDMA just aren't coded into the BIOS. This quoted text here is the final conclusion of one of the users:
in these cases you have to hack that feature back in with custom assembly code. So there's no easy option.
well, adding a missin […]
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in these cases you have to hack that feature back in with custom assembly code. So there's no easy option.
well, adding a missing item back in is almost impossible. I got limited knowledge of ASM and tried that for like 3 years.
the main problem is that the system.bin doesn't have any room near the items, so there's simply no space to add something back in.
however some award bios got 5 "leftover" items which one can put to good use. that's the way i did it till now
i stored my custom code as ISA or PCI option rom (think of it as a module which for example contains the ROM of some onboard controller). that code read the CMOS and that way i knew which value the "new" item was set to.
however, that option rom is executes after POST, right before OS boot. so that may be too late to change UDMA values.
i've not tried to sneak code into the early boot process yet.
I'm latching on to the part where he says some BIOS have "leftover" items. Perhaps this is the case with mine?
Below is a screenshot of some info on my BIOS that MODBIN displays:
Spoiler

I don't suppose there's anyone here with knowledge of how to write custom assembly language and inject that back into the BIOS? Bear in mind, I have zero idea how long of a process that is. If this is like a month like learning process and coding procedure then I don't expect anyone to jump in and do it for me.
I have tried to sign up for bios-mods.com because on the forum there is a section there with requests such as mine but after 72 hours and after using the activation email, my account is still not validated. Anyone familiar with that site and know what could be going on?