@retro games 100 What a pity I haven't got SYL8884PCI-EIO (I have: Shuttle Hot-433, Elitegroup UM8810P-AIO, Gigabyte GA - 486AM). I suppose that this is processor related problem. You have to find better one. I have got five 5x86 133MHz ADZ but only two work fine at 180MHz.
@leileilol Can you list your 486 specification please? I don't think that this is PCI performance problem. Those old machines have slow memory so you can't reach full PCI speed.
Maybe you ran timedemo at vid_mode 0 (320x200)? I have checked my results again. This is what I obtained:
5x86 133MHz ADZ @ 180MHz full stable bios settings:
vid_mode 17 (320x240): 11,6fps
When I set more agressive cache timings (dos still stable but BSOD when booting to WIN95) I obtained:
vid_mode 17 12,3fps

vid_mode 0 (320x200) 14,3fps

@Tetrium This forum is the biggest repository of knowledge i have ever seen. My first computer was 5x86 133MHz but i hadn't got knowledge to overclock it. Now i want to catch up. (;
I have made some progress in Peltier.
First of all i had to make insulating frame for CPU and Peltier module. This is very important because condensed water can damage computer (this is active heat pump so temperature on cold side can drop below ambient temperature).

Peltier in frame

Peltier, CPU bounded together in frame


Photo above shows my first mistake. I placed Peltier hot side to CPU. I realized that something is wrong when computer hang up at 133MHz. Fortunately I used Peltier in this position for a short time and CPU still work correctly.
Because of power lack standard power supply 12V rail (only 9A) i had to use additional power supply for Peltier.

This allowed me to reach full stable 5x86 133MHz@180MHz_4V in home.
Warning
[boring part]
I use Peltier TEC1-1270 (89W) in my project. You can read its datasheet here:
http://www.hebeiltd.com.cn/peltier.datasheet/TEC1-12710.pdf
From this datasheet you can evaluate expected temperature on Peltier cold side.
Sketch of the calculations:
Up-voltage applied to Peltier
Rp-Peltier resistance
Ic-Peltier current
Qj-Joule heat (Qj=Ic^2 *Rp)
Th-Peltier hot side temperature
Tc-Peltier cold side temperature
dT-temperature diference between cold and hot side of Peltier
Ta-ambient temperature
Qcpu-heat produced by overclocked CPU
TDP-heat produced by non overclocked CPU
fs-non overclocked CPU frequency
fo-overclocked CPU frequency
Us-non overclocked CPU voltage
Uo-overclocked CPU voltage
Qh-heat transferred to cooler
Rw-cooler thermal resistance [C/W]
Ic=Up/Rp=12/1,24=9.68A (near optimal Imax=10.5A)
Qj=9.68^2*1.24=116.44W
TDP=3.7W, fo=180Mhz, fs=133MHz, Uo=4V, Us=3.45V
Qcpu=TDP*(fo\fs)*(Uo\Us)^2
Qcpu@180MHz_4V=6.74W
Qh=Qj+Qcpu
Qh=123.18W
ambient temperature in my house Ta =18C, Rw=0.5[C/W]
Th=Qh*Rw+Ta=79.59C
Tc=Th-dT (dT=70C from datasheet)
Tc=79.59-70=9,58C, so my CPU should have temperature below ambient temperature.
I had problem finding small, cheap and eficient power supply. Finally I decided to try 5V form internal power supply (full satisfactory 22A).
Additional calculations proved that this is better way.
Ic=4.63A
Qj=23.16W
Qh=29.9W
Th=32.95C dT=35C
Tc=32.95-35=-2,05C (28.31F)!
[/boring part]
Peltier connected to 5V internal power supply rail.

Now my CPU is stable in home at 180MHz and 3.6V! I can also close my case because i don't use external power suply any more. I haven't tested my system outside yet, because i'm waiting for lower temperature (current temperature is above 0C). In home 200Mhz still doesn't work. I suppose i need better CPU.
I'm going to make some control logic (control current by PWM, measure CPU temperature etc.) for my Peltier module. This will allow me to get real fedback.
HNY Vogons! (: